Re: Baffled!! The truck won't fire.
Disregarding everything else (sounds like there was a lot going on - and things tend to get misinterpreted in the heat of battle) and just using the info contained in the last couple of sentences - I would lean towards a head gasket issue.
There are not many things that can make a SBC overheat (or appear to over heat) while idling.
The three things you observed; a sudden spike in coolant temperature indication, excess pressure in the coolant system and maybe most importantly, the fact that what was venting off did not appear to be steam - would indicate a combustion space to coolant system leak in the head gasket. To me anyway, someone else may have a less tragic diagnosis.
There is no way your radiator could be plugged up up - right? It's only 6 months old. Try pulling the t-stat and looking down into the outlet tank. Rev the engine and note whether the level in the outlet side drops quickly and about at least 2-3 inches. Also confirm that coolant can be seen gushing from the ends of the tubes into the tank.
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